Effect of Chlorine Released during Hydrodechlorination of Chlorobenzene over Pd, Pt and Rh Supported Catalysts |
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| Authors: | José Luis Benitez Gloria Del Angel |
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| Affiliation: | (1) Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, India; |
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| Abstract: | Chlorobenzene hydrodechlorination in liquid phase has been studied. Chlorine released during the reaction inhibits conversion in large metallic particles. It was found comparing the behavior of Pd/SiO2, Pd/Al2O3 and Pd/C catalysts that the support plays the role of a chlorine trap. The activity for Pt, Rh and Pd at similar dispersions corresponds to the chlorine adsorption affinity of the metals. |
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| Keywords: | Chlorobenzene hydrodechlorination dispersion effect support effect Pd/C Rh/C Pt/C |
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