Transition Metal-Catalyzed Enantioselective Synthesis of Chiral Five- and Six-Membered Benzo O-heterocycles |
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| Authors: | Dr. Lu Yang Xiayu Liang Yuyang Ding Prof. Xinran Li Xuefeng Li Prof. Qingle Zeng |
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| Affiliation: | 1. Key Laboratory of General Chemistry of the National Ethnic Affairs Commission, Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Chengdu, 610041 People's Republic of China;2. College of Materials, Chemistry & Chemical Engineering, Chengdu, 610059 People's Republic of China |
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| Abstract: | Enantiomerically enriched five- and six-membered benzo oxygen heterocycles are privileged architectures in functional organic molecules. Over the last several years, many effective methods have been established to access these compounds. However, comprehensive documents cover updated methodologies still in highly demand. In this review, recent transition metal catalyzed transformations lead to chiral five- and six-membered benzo oxygen heterocycles are presented. The mechanism and chirality transfer or control processes are also discussed in details. |
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| Keywords: | transition metal-catalysis enantioselective synthesis chiral benzo O-heterocycles mechanism |
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