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Isolation and characterization of a carbene derivative of La@C82 |
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| Authors: | Maeda Yutaka Matsunaga Yoichiro Wakahara Takatsugu Takahashi Satomi Tsuchiya Takahiro Ishitsuka Midori O Hasegawa Tadashi Akasaka Takeshi Liu Michael T H Kokura Kisato Horn Ernst Yoza Kenji Kato Tatsuhisa Okubo Shingo Kobayashi Kaoru Nagase Shigeru Yamamoto Kazunori |
| Institution: | Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. |
| Abstract: | The photochemical reaction of La@C82 with 2-adamantane-2,3-3H]-diazirine affords adduct 2, La@C82(Ad), in a quantitative and highly selective manner. The structure of compound 2 is confirmed by ESR, MS, and UV-vis-NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported. |
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