| 聚N-[5-(8-羟基喹啉)甲基]苯胺/介孔五氧化二钒杂化材料的制备与表征 |
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| 引用本文： | 赵晶,王庚超,李星玮,张志平.聚N-[5-(8-羟基喹啉)甲基]苯胺/介孔五氧化二钒杂化材料的制备与表征[J].高分子学报,2007(7):672-675. |
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| 作者姓名： | 赵晶 王庚超 李星玮 张志平 |
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| 作者单位： | 华东理工大学材料科学与工程学院,超细材料制备与应用教育部重点实验室,上海,200237 |
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| 基金项目： | 国家自然科学基金
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上海市重点基础研究项目 |
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| 摘 要： | 采用原位插层聚合法制备出层状有序的聚N-5-(8-羟基喹啉)甲基]苯胺/介孔五氧化二钒(PNQA/Meso-V2O5)杂化材料.结果显示,PNQA插入后,Meso-V2O5的层间距由2.4nm增加到2.81nm,得到的杂化材料仍保持良好的层状结构.杂化材料的室温电导率比Meso-V2O5高出3个数量级.荧光分析表明,在乙醇介质中杂化材料的发射谱带与PNQA相比蓝移22nm,杂化材料的荧光量子产率(26%)明显高于PNQA(10%).
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| 关 键 词： | 导电聚合物 介孔五氧化二钒 杂化材料 插层聚合 |
| 修稿时间： | 2006-08-222006-10-26 |
THE SYNTHESIS AND CHARACTERIZATION OF POLY(N-[5-(8-HYDROXYQUINOLINE)METHYL]ANILINE)/MESOSTRUCTURED V2O5 HYBRID MATERIALS |
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| ZHAO Jing,WANG Gengchao,LI Xingwei,ZHANG Zhiping.THE SYNTHESIS AND CHARACTERIZATION OF POLY(N-[5-(8-HYDROXYQUINOLINE)METHYL]ANILINE)/MESOSTRUCTURED V2O5 HYBRID MATERIALS[J].Acta Polymerica Sinica,2007(7):672-675. |
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| Authors: | ZHAO Jing WANG Gengchao LI Xingwei ZHANG Zhiping |
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| Abstract: | Poly(N-5-(8-hydroxyquinoline)methyl]aniline)/Meso-V_2O_5 (PNQA/Meso-V_2O_5) hybrid materials were synthesized by intercalative polymerization method.The results show that the interlayer spacing of the Meso-V_2O_5 has increased from 2.40 nm to 2.81 nm, while the lamellar of V_2O_5 is preserved.The electrical conductivity of the hybrid materials is by 3 orders of magnitude higher than that of the Meso-V_2O_5. The photoluminescence analysis indicates that the emission band of the hybrid is blue shifted 22 nm in comparison with that of pure PNQA,and the hybrid gives a quantum yield of 26%,which is higher than that (10%) of PNQA in ethanol. |
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| Keywords: | Conducting polymer Mesostructured vanadium pentoxide Hybrid materials Intercalative polymerization |
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