| 反应SO2+OH+M的动力学研究(Ⅰ) |
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| 引用本文： | 陈馨国,施树浩,邱联雄.反应SO2+OH+M的动力学研究(Ⅰ)[J].物理化学学报,1988,4(6):600-605. |
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| 作者姓名： | 陈馨国 施树浩 邱联雄 |
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| 作者单位： | Department of Chemistry; Graduate School of Academic Sinica |
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| 摘 要： | 用放电流动-共振荧光方法(DF-RF)研究SO_2+OH+M反应。讨论了壁反应, 扩散和副反应对速率常数测定的影响, 确定该反应在298 K下氩和氮气氛中反应比速的数据分别是(1.5±0.32)×10~(-31)cm~6molec~(-2)s~(-1)和(3.6±0.79)×10~(-31)cm~6molec~(-2)s~(-1)。
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| 收稿时间： | 1987-05-16 |
| 修稿时间： | 1987-11-14 |
KINETIC RESEARCH OF THE REACTION OF SO2+OH+M(Ⅰ) |
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| Chen Xinguo,Shi Shuhao,Qiu Lianxiong.KINETIC RESEARCH OF THE REACTION OF SO2+OH+M(Ⅰ)[J].Acta Physico-Chimica Sinica,1988,4(6):600-605. |
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| Authors: | Chen Xinguo Shi Shuhao Qiu Lianxiong |
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| Institution: | Department of Chemistry; Graduate School of Academic Sinica |
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| Abstract: | By using the method of Discharge Flow-Resonance Fluorescence, the reaction of OH+SO_2+M was studied. The effect of wall reacton, diffusion and side reaction on the rate constants of the reaction was discussed. In the atmosphere of Ar or N_2, at 298K, the measured rate constants of the reaction were (1.5+0.32) × 10~(-31) cm~6 molec~(-2) s~(-1) and (3.6±0.79)×10~(-31)cm~6 melec~(-2) s~(-1), respectively. |
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