| 新型含环氧端基聚芳醚酮的合成及表征 |
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| 引用本文： | 宣英男,蹇锡高,田世哲.新型含环氧端基聚芳醚酮的合成及表征[J].高分子学报,2000,31(4):407-410. |
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| 作者姓名： | 宣英男 蹇锡高 田世哲 |
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| 作者单位： | 大连理工大学化工学院高分子材料系,大连,116012 |
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| 基金项目： | 国家“九五”攻关项目! (基金号 97 56 4 0 1 0 7)部分工作 |
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| 摘 要： | 以 4,4′ 二氟二苯酮和 4 (4 羟基苯基 ) 2 ,3 二氮杂萘 1 酮经亲核取代逐步聚合制得含二氮杂萘酮结构的聚芳醚酮低聚物 ,再与环氧氯丙烷反应制得了所需分子量的含环氧端基的聚芳醚酮 (E PPEK) .用FT IR和1H NMR表征了分子链结构 ,并测定了聚合物的玻璃化转变温度Tg 和溶解性 .
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| 关 键 词： | 环氧端基 聚芳醚酮 合成 |
SYNTHESIS AND CHARACTERIZATION OF A NOVEL EPOXY-TERMINATED POLY(ARYL ETHER KETONE) |
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| XUAN Yingna,JIAN Xigao,TIAN Shizhe.SYNTHESIS AND CHARACTERIZATION OF A NOVEL EPOXY-TERMINATED POLY(ARYL ETHER KETONE)[J].Acta Polymerica Sinica,2000,31(4):407-410. |
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| Authors: | XUAN Yingna JIAN Xigao TIAN Shizhe |
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| Abstract: | A novel epoxy\|terminated polyaryletherketone(E\|PPEK)was synthesized by the reaction of epichlorohydrin with PPEK oligomer prepared by nucleophilic substitution of 4,4′ \|difluorobenzophenone(DFK) with 4\|(4\|hydroxyphenyl)\| 2,3 \|phthalazine\|1\|one.E\|PPEK samples were characterized by FT\|IR and 1H\|NMR spectra,and their solubility was also determied. |
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| Keywords: | Epoxy\|terminated Poly(aryl ether ketone) Synthesis |
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