Crystal structure of octapotassium octasulfatodiceriate pentahydrate |
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| Authors: | L F Malakhova O A Alekseeva N G Furmanova S N Bocharov L Yu Kryuchkova |
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| Institution: | 1.Shubnikov Institute of Crystallography,Russian Academy of Sciences,Moscow,Russia;2.St. Petersburg State University,St. Petersburg,Russia |
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| Abstract: | Single crystals without Co and Ni have been crystallized by the substitution method in the K2Ni(SO4)2-Ce(SO4)2-H2SO4-H2O system using K2Co(SO4)2 · 6H2O, K2 (Co,Ni)(SO4)2 · 6H2O, or K2Ni(SO4)2 · 6H2O as protocrystals. The structure of the single crystals obtained has been established by X-ray diffraction analysis. The
crystal structure contains dimer complex anions Ce2(μ-SO4)2(SO4)6]8−, K+ cations, and crystallization water molecules. |
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