Controllable synthesis and characterization of tube brush-like ZnO nanowires produced via a simple chemical vapor deposition method |
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Authors: | Ya-Qing Bie Zhi-Min Liao Hong-Jun Xu Xin-Zheng Zhang Xu-Dong Shan Da-Peng Yu |
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Institution: | (1) Nanoscale Materials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba Ibaraki, 305-0044, Japan |
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Abstract: | Tube brush-like ZnO nanostructures were synthesized by a simple chemical vapor deposition method with Zn and ZnO as precursors.
These special ZnO nanostructures were characterized by Scanning Electron Microscope, Energy Dispersive X-ray Spectroscopy,
High Resolution Transmission Electron Microscope and Cathodoluminescence (CL) techniques. Empty backbones or comb ribbons
backbones were found inside the tube brush-like ZnO structures and fuzzy ZnO nanowires outside. Outside ZnO nanowires grow
along the c axis and show green CL emission. The growth mechanism of the hierarchical ZnO nanostructures was investigated
by a series of experiments at different growth temperatures and different duration times, and a secondary growth mechanism
has been proposed and discussed. |
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Keywords: | |
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