| 可溶性聚对苯乙炔衍生物的合成 |
| |
| 引用本文： | 王建营,李银奎,胡文祥,龙永福. 可溶性聚对苯乙炔衍生物的合成[J]. 高等学校化学学报, 1998, 19(10): 1703-1705 |
| |
| 作者姓名： | 王建营 李银奎 胡文祥 龙永福 |
| |
| 作者单位： | 1. 国防科工委军事医药研究发展中心, 北京, 100101;2. 国防科技大学材料工程与应用化学系, 长沙, 410073 |
| |
| 摘 要： | 聚对苯乙炔（ＰＰＶ）具有独特的光电性能，经强氧化剂掺杂后是一类重要的导电材料［１］，而且具有良好的非线性光学（ＮＬＯ）性质［２］，也是目前性能最好的高分子电致发光材料［３，４］．可溶性的ＰＰＶ衍生物有望在显示领域广泛应用，从而成为电致发光领域研究的新...
|
| 关 键 词： | 聚对苯乙炔 烷氧取代基 脱氯化氢反应 |
| 收稿时间： | 1997-11-10 |
| 修稿时间： | 1997-11-10 |
The Synthesis of Soluble Poly (p-phenylene vinylene) Derivatives |
| |
| WANG Jian-Ying,LI Yin-Kui,HU Wen-Xiang,LONG Yong-Fu. The Synthesis of Soluble Poly (p-phenylene vinylene) Derivatives[J]. Chemical Research In Chinese Universities, 1998, 19(10): 1703-1705 |
| |
| Authors: | WANG Jian-Ying LI Yin-Kui HU Wen-Xiang LONG Yong-Fu |
| |
| Affiliation: | 1. The Centre of Research and Development of Medicine Pharmaceuticals, Commission of Science, Technology and Industry for National Defence, Beijing, 100101;2. Department of Materials Engineering and Applied Chemistry, National University of Defence Technology, Changsha, 410073 |
| |
| Abstract: | Poly(2 methoxy 5 hexyloxy p phenylene vinylene) and poly(2 methoxy 5 nonyloxy p phenylene vinylene) were synthesized through dehydrochlorination with p methoxy phenol as raw materials. The effect of solvents and substituents on polymerization and polymer solubility was discussed. The structure of polymers was identified by UV/Vis, IR and 1H NMR. |
| |
| Keywords: | Poly( p phenylene vinylene) Alkoxy substituents Dehydrochlorination |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
|
点击此处可从《高等学校化学学报》下载全文 |
|
