Nuclear magnetic relaxation in ferrimagnetic Y3Fe5−x SixO12 films

The effect of silicon impurities on the damping of spin-echo signals from the ⁵⁷Fe nuclei of tetrahedral Fe³⁺ ions in epitaxial yttrium-iron-garnet films was investigated. It was found that for silicon concentrations 0.015⩽x⩽0.037 the damping of the spin echo is a two-component process, which made it possible to separate nuclei into two types, differing by both the longitudinal and transverse magnetic relaxation times. For silicon concentrations 0.044⩽x⩽0.073 the decay of the echo can be described by one exponential and all nuclei in the sample have the same transverse relaxation times and the same longitudinal relaxation times. The experimental results are interpreted on the basis of the supposition that impurity “macromolecules” form around the Si⁴⁺ ions. The relaxation times of the iron nuclei in a “macromolecule” are much shorter than the relaxation times of iron nuclei belonging to the matrix ions. The radius of a “macromolecule” is estimated on the basis of percolation theory. Fiz. Tverd. Tela (St. Petersburg) 40, 1494–1497 (August 1998)