1,2-Ditellurolane: A new synthetic method, structure and chemical reactions |
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| Authors: | N. V. Russavskaya A. V. Elaev V. A. Grabel’nyh E. R. Zhanchipova E. P. Levanova L. V. Klyba E. N. Sukhomazova S. G. Shevchenko T. I. Vacul’skaya A. I. Albanov N. A. Korchevin |
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| Affiliation: | (1) A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk, 664033 |
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| Abstract: | A simple method for the synthesis of 1,2-ditellurolane is proposed, based on the reaction of elemental tellurium with 1,3-dihalopropane in a system of hydrazine hydrate and alkali followed by the effect of organic solvent on the first formed poly(trimethyleneditellurides). The products of the oxidation and reduction of 1,2-ditellurolane were characterized and its spectral characteristics were analyzed. Dedicated To Academician Of The Russian Academy Of Science Mikhail Grigor’evich Voronkov on his 85th Birthday. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, 1705–1713, November 2006. |
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| Keywords: | 1,3-bis((methyltelluro)propane hydrazine hydrate 1,2-ditellurolane 1,3-propaneditelluric acid tellurium telluretane quantum chemical-calculations |
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