1,2-Ditellurolane: A new synthetic method, structure and chemical reactions |
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| Authors: | N V Russavskaya A V Elaev V A Grabel’nyh E R Zhanchipova E P Levanova L V Klyba E N Sukhomazova S G Shevchenko T I Vacul’skaya A I Albanov N A Korchevin |
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| Institution: | (1) A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk, 664033 |
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| Abstract: | A simple method for the synthesis of 1,2-ditellurolane is proposed, based on the reaction of elemental tellurium with 1,3-dihalopropane
in a system of hydrazine hydrate and alkali followed by the effect of organic solvent on the first formed poly(trimethyleneditellurides).
The products of the oxidation and reduction of 1,2-ditellurolane were characterized and its spectral characteristics were
analyzed.
Dedicated To Academician Of The Russian Academy Of Science Mikhail Grigor’evich Voronkov on his 85th Birthday.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, 1705–1713, November 2006. |
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| Keywords: | 1 3-bis((methyltelluro)propane hydrazine hydrate 1 2-ditellurolane 1 3-propaneditelluric acid tellurium telluretane quantum chemical-calculations |
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