Palladium-catalyzed oxidative sp2 C-H bond acylation with alcohols |
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| Authors: | Xiao Fuhong Shuai Qi Zhao Feng Baslé Olivier Deng Guojun Li Chao-Jun |
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| Institution: | Key Laboratory for Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China. |
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| Abstract: | An efficient method was developed for the direct acylation of arene sp(2) C-H bonds with alcohols using palladium chloride as a catalyst and peroxide as the oxidant. The alcohols were oxidized to their corresponding aldehydes in situ and efficiently coupled with 2-arylpyridines to give aryl ketones in chlorobenzene. |
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