Synthesis and Structure of Tri(p-tolyl)antimony Dichloride |
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| Authors: | V V Sharutin O K Sharutina A P Pakusina T P Platonova V K Bel'skii |
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| Institution: | (1) Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia |
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| Abstract: | Tri(p-tolyl)antimony dichloride was prepared by oxidation of tri(p-tolyl)stibine with chlorine or copper(II) chloride. As found by X-ray diffraction analysis, the antimony atom in tri(p-tolyl)antimony dichloride has the configuration of trigonal bipyramid with axially located chlorine atoms. The Sb-Cl and Sb-C distances are 2.476(2) and 2.104(7) Å, and the CSbC and ClSbCl angles are 120 and 180°, respectively. |
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