Regio- and diastereoselective boron-mediated aldol reactions of chiral α,β,γ,δ-unsaturated N-acyloxazolidinones |
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| Authors: | James M Takacs Mohamad R Jaber Benjamin J Swanson Steven J Mehrman |
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| Affiliation: | Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588-0304, USA |
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| Abstract: | Chiral N-acyloxazolidinones derived from conjugated dienoic acids undergo boron-mediated aldol condensation in good yield and with high regio- and diastereoselectivity to provide a convenient method for introducing a 1,3-diene subunit. The condensation of a homologous triene derivative is also described. |
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