| 铜铬类水滑石的表征及其催化性能 |
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| 引用本文： | 程淑艳,谢鲜梅,廖家友,严 凯,安 霞,吴 旭. 铜铬类水滑石的表征及其催化性能[J]. 无机化学学报, 2009, 25(12): 2220-2224 |
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| 作者姓名： | 程淑艳 谢鲜梅 廖家友 严 凯 安 霞 吴 旭 |
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| 作者单位： | 太原理工大学化学化工学院,太原,030024 |
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| 基金项目： | 国家自然科学基金，山西省自然科学基金 |
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| 摘 要： | The CuCr-Hydrotalcite-like Compounds were synthesized by co-precipitation method. The samples were characterized by XRD, FTIR and N2-adsorption/desorption measurements. The catalytic performance of the material synthesized was evaluated for the synthesis of benzion methyl ether with benzaldehyde and methanol. The result show that well crystallized hydrotalcites are obtained when nCu/nCr molar ratio is 2.0 and final value of pH is 4.3±0.2. The crystal shape is remained the same while crystallinity, surface area, pore structure and activity vary with the molar ratio of Cu to Cr. The catalytic activity is the best when the molar ratio of Cu to Cr is 2.0 at 50 ℃ andreaction time is 90 min. The highest conversion of benzaldehyde could reach 89.56％,while the selectivity of benzoin methyl ether is nearly 100％.
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| 关 键 词： | 铜铬类水滑石； 合成； 催化； 苯甲醛； 安息香甲醚 |
Synthesis and Catalytic Application of Copper Chromic-Hydrotalcite-Like Compounds |
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| CHENG Shu-Yan,XIE Xian-Mei,LIAO Jia-You,YAN Kai,AN Xia and WU Xu. Synthesis and Catalytic Application of Copper Chromic-Hydrotalcite-Like Compounds[J]. Chinese Journal of Inorganic Chemistry, 2009, 25(12): 2220-2224 |
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| Authors: | CHENG Shu-Yan XIE Xian-Mei LIAO Jia-You YAN Kai AN Xia WU Xu |
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| Affiliation: | College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024 and College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024 |
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| Abstract: | The CuCr-Hydrotalcite-like Compounds were synthesized by CO-precipitation method.The samples were characterized by XRD,FTIR and N2-adsorption/desorption measurements.The catalytic performance of the material synthesized Was evaluated for the synthesis of benzion methyl ether with benzaldehyde and methanol.The result show that well crystallized hydrotalcites are obtained when n_(Cu)/n_(Cr)molar ratio is 2.0 and final value of pH is 4.3±0.2.The crystal shape is remained the same while crystallinity,surface area,pore structure and activity vary with the molar ratio of Cu to Cr.The catalytic activity is the best when the molar ratio of Cu to Cr is 2.0 at 50 ℃andreaction time is 90 min.The highest conversion of benzaldehyde could reach 89.56%,while the selectivity of benzoin methyl ether is nearly 100%. |
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| Keywords: | CuCr-hydrotalcite-like compounds synthesized catalysis benzaldehyde benzoin methyl ether |
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