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Direct preparation of copper organometallics bearing an aldehyde function via an iodine-copper exchange
Authors:Yang Xiaoyin  Knochel Paul
Institution:Department Chemie, Ludwig-Maximilians-Universit?t München, Butenandtstr. 5-13, Haus F, 81377 München, Germany.
Abstract:The iodine-copper exchange reaction allows the direct preparation of various aryl, heteroaryl and alkenyl cuprates bearing a formyl group, thus allowing a direct synthesis of polyfunctional aldehydes without the need of protecting groups or an additional oxidation step.
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