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Ethylene dimerization and polymerization over transition metal-exchanged montmorillonite catalysts
Authors:Jong Rack Sohn and Man Young Park
Institution:(1) Department of Industrial Chemistry, Engineering College, Kyungpook National University, 702-701 Taegu, Korea
Abstract:It has been found that dimerization of ethylene ton-butenes proceeds selectively over Ni2+-Mont. Over Cr3+-Mont, extensive polymerization occurs and the polyethylene produced shows a high melting point and density. The catalytic activities for ethylene dimerization and polymerization are closely correlated with the acidity of catalysts.
Keywords:Clay catalyst  ethylene dimerization  ethylene polymerization  montmorillonite
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