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Anisotropy in Borrmann spectroscopy
Authors:S P Collins  M Tolkiehn  T Laurus  V E Dmitrienko
Institution:1.Diamond House, Harwell Science and Innovation Campus,Diamond Light Source Ltd.,Didcot,UK;2.Deutsches Elektronensynchrotron DESY, FS-DO,Hamburg,Germany;3.A. V. Shubnikov Institute of Crystallography,Moscow,Russia
Abstract:In this paper we introduce Borrmann Spectroscopy as a method for measuring X-ray absorption spectra under conditions of an exotic wave field, namely, a coherent superposition of two plane waves. The essential features of the Borrmann Effect (also known as anomalous transmission) are outlined. We show that the Borrmann Effect can lead to a very strong relative enhancement of quadrupole absorption. After describing some early results in this field, and some general considerations of multiple-wave absorption, we contrast recent results on anisotropy in Borrmann spectroscopy with normal absorption. Despite the qualitative success of a simple model for quadrupole enhancement, temperature dependence and anisotropy, a general theory of the Borrmann Effect is required which includes anisotropic and non-dipolar scattering. We outline some first steps towards such a theory.
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