An unexpected highly stereoselective double aza-Baylis-Hillman reaction of sulfonated imines with phenyl vinyl ketone |
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| Authors: | Shi Min Xu Yong-Mei |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai 200032, China. mshi@pub.sioc.ac.cn |
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| Abstract: | The aza-Baylis-Hillman reaction of N-sulfonated imine with phenyl vinyl ketone gave the double aza-Baylis-Hillman adduct in good yields with excellent stereoselectivities in the presence of Lewis base 1,4-diazabicyclo[2.2.2]octane. |
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