A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism |
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| Authors: | Wang Dongping Shiraishi Yasuhiro Hirai Takayuki |
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| Affiliation: | Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Japan. |
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| Abstract: | A boradiazaindacene (BODIPY) derivative containing a simple NO bidentate ligand shows a Cu(2+)-selective fluorescence in aqueous media. This is promoted via a coordination of Cu(2+) followed by oxidative dehydrogenation of an amine moiety, leading to a formation of a fluorescent Cu(+)-Schiff base complex. |
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