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Plasma Treatment of Ni Catalyst for Partial Oxidation of Methane
作者姓名:YanruZhu  ZhenhuaLi  YuhongZhou  HaitaoWang
作者单位:KeyLabforGreenChemicalTechnology,SchoolofChemicalEngineeringandTechnology,TianjinUniversity,Tianjin300072,China
摘    要:The 10%Ni/Al2O3 catalyst for partial oxidation of methane was treated by DBD (dielectric barrier discharge) plasma in a continuous system under atmospheric pressure and room temperature by flowing He. It was found that 10%Ni/Al2O3 catalyst treated by plasma presents a higher catalytic activity and an enhanced stability than the catalysts prepared without plasma treatment. The methane conversion over the catalyst treated by plasma is 3%-5% higher than the catalysts untreated by plasma. Moreover,the enhanced dispersion of the catalyst can be achieved by plasma treatment, which can improve the interaction between active species and supports, catalytic activity and the resistance to carbon deposition.

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Plasma Treatment of Ni Catalyst for Partial Oxidation of Methane
YanruZhu ZhenhuaLi YuhongZhou HaitaoWang.Plasma Treatment of Ni Catalyst for Partial Oxidation of Methane[J].Journal of Natural Gas Chemistry,2005,14(1):1-3.
Authors:Yanru Zhu  Zhenhua Li  Yuhong Zhou  Haitao Wang
Institution:Key Lab for Green Chemical Technology, School of Chemical Engineering and Technology,
Abstract:The 10%Ni/Al2Os catalyst for partial oxidation of methane was treated by DBD (dielectric barrier discharge) plasma in a continuous system under atmospheric pressure and room temperature by flowing He. It was found that 10%Ni/Al2O3 catalyst treated by plasma presents a higher catalytic activity and an enhanced stability than the catalysts prepared without plasma treatment. The methane conversion over the catalyst treated by plasma is 3%-5% higher than the catalysts untreated by plasma. Moreover, the enhanced dispersion of the catalyst can be achieved by plasma treatment, which can improve the interaction between active species and supports, catalytic activity and the resistance to carbon deposition.
Keywords:plasma treatment  methane  synthesis gas  partial oxidation  carbon deposition
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