Bromination of ketones with the systems H2O2-LiBr-CeIII and H2O2-LiBr-CeIV |
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| Authors: | G I Nikishin L L Sokova N I Kapustina |
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| Institution: | 1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
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| Abstract: | A new method for the synthesis of α-bromoketones was suggested. The C5-C11 linear and branched ketones in the reaction with the systems H2O2-LiBr-CeIII and H2O2-LiBr-CeIV in acetonitrile were brominated at α-position. The reaction is highly selective. |
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