Zero-field optical detected magnetic resonance of [70]-fullerene |
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| Authors: | C Saal N Weiden K -P Dinse |
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| Institution: | 1. Institut für Physikalische Chemie, Technische Hochschule Darmstadt, Petersenstra?e 20, 64287, Darmstadt, Germany
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| Abstract: | The phosphorescence spectrum of 70]-fullerene in a glassy toluene matrix has been investigated at 77, 4.2 and 1.2 K. At 77 K, only one decay time (47.0 ms) has been observed while at 4.2 and 1.2 K two decay times (46.7, 5.6 ms and 46.6, 24.2 ms, respectively) were recorded. The zero field splitting parameters |D|=0.00489(25) cm?1 and |E|=0.00135(7) cm?1 were measured at 1.2 K using a pulsed ODMR technique. |
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