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Synthesis of asymmetrical thioethers with sulfinamides as the sulfenylation agent under metal-free conditions |
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| Authors: | Long-jun Ma Guang-xun Li Jin Huang Jin Zhu Zhuo Tang |
| Institution: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, Sichuan 610041, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Science, Chengdu, Sichuan 610041, China |
| Abstract: | Using sulfinamides as a new reagent for preparation of asymmetrical thioethers has been developed under metal-free conditions. The reactions proceeded smoothly without the use of stinky thiophenol, highly toxic sulfonyl chloride or oxidant. Such a simple, efficient transformation provides an attractive approach to various diaryl sulfides in good to excellent yields. |
| Keywords: | Sulfinamides Sulfenylation agent Metal-free Asymmetrical thioethers |
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