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First total synthesis of Brevipolide N and total synthesis of Brevipolide M |
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| Authors: | Kasa Shiva Raju Gowravaram Sabitha |
| Institution: | Natural Products Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | The First total Synthesis of Brevipolide N and total Synthesis Brevipolide M have been accomplished from commercially available d-Mannitol. The key features of the syntheses are the use of Horner–Wadsworth–Emmons olefination, Noyori reduction, Acid catalyzed epoxide opening and Lindlars reaction. |
| Keywords: | Brevipolides δ-Lactone HWE olefination Noyori reduction Cyclic ether Epoxide opening Lindlars reaction |
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