| THE ESR STUDY OF SOME DICYCLOPENTA-DIENYL TITANIUM HALIDE COMPLEXES |
| |
| 引用本文： | 白令君,刘风全,王积涛. THE ESR STUDY OF SOME DICYCLOPENTA-DIENYL TITANIUM HALIDE COMPLEXES[J]. 中国科学B辑(英文版), 1991, 0(3) |
| |
| 作者姓名： | 白令君 刘风全 王积涛 |
| |
| 作者单位： | Department of Chemistry，Nankai University，Department of Chemistry，Nankai University，Department of Chemistry，Nankai University Tianjin 300071，PRC，Tianjin 300071，PRC，Tianjin 300071，PRC |
| |
| 摘 要： | The ESR spectra of some [Cp_2Ti(L)X] complexes (Cp: C_5H_5, MeC_5H_4; L: phosphane,isocyanide, pyridine, amine and carbon monoxide; X: F, Cl, Br, I) have been obtained.When X is Cl, Br or I, the linear relationships between the g value and hyperfine couplingcoustant a(Ti) are explained in terms of the electron character of the L ligand and the ESRspectral trends of the complexes are studied.
|
THE ESR STUDY OF SOME DICYCLOPENTA-DIENYL TITANIUM HALIDE COMPLEXES |
| |
| BAI LING-JUN,LIU FENG-QUAN,WANG JI-TAO. THE ESR STUDY OF SOME DICYCLOPENTA-DIENYL TITANIUM HALIDE COMPLEXES[J]. Science in China(Chemistry), 1991, 0(3) |
| |
| Authors: | BAI LING-JUN LIU FENG-QUAN WANG JI-TAO |
| |
| Affiliation: | BAI LING-JUN,LIU FENG-QUAN,WANG JI-TAO Department of Chemistry,Nankai University,Tianjin 300071,PRC |
| |
| Abstract: | The ESR spectra of some [Cp_2Ti(L)X] complexes (Cp: C_5H_5, MeC_5H_4; L: phosphane,isocyanide, pyridine, amine and carbon monoxide; X: F, Cl, Br, I) have been obtained.When X is Cl, Br or I, the linear relationships between the g value and hyperfine couplingcoustant a(Ti) are explained in terms of the electron character of the L ligand and the ESRspectral trends of the complexes are studied. |
| |
| Keywords: | dicyclopentadienyl titanium halide ESR spectra |
| 本文献已被 CNKI 等数据库收录！ |
|
