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Isophthaldihydroxamic acid as a spectrophotometric reagent for the determination of molybdate ion
Authors:F Salinas  M Jimnez-Arrabal
Institution:Department of Analytical Chemistry, Faculty of Sciences, University of Extremadura, Badajoz, Spain
Abstract:Isophthaldihydroxamic acid produces colored solutions with molybdate ions in basic medium. The resultant product is extracted into a toluenic solution of trioctylmethylammonium chloride (Adogen). The yellow color obtained in the organic solvent (molar absorptivity 6.050 liters · mol−1 · cm−1 at a wavelength of 350 nm) has been used for the spectrophotometric determination of molybdenum in the range of 1.3 to 6 ppm with a relative error of the mean value of 1.3%.
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