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Synthesis and Characterization of a Noncovalently Linked Porphyrin-[1,2-(1-acridin-10′-yl-2-aza-2-methylprop-1,3-ylene)-fullerene]Dyad
引用本文:项云,魏先文,张新明,查庆庆,孙健,尹桂,徐正.Synthesis and Characterization of a Noncovalently Linked Porphyrin-[1,2-(1-acridin-10′-yl-2-aza-2-methylprop-1,3-ylene)-fullerene]Dyad[J].中国化学,2006(7).
作者姓名:项云  魏先文  张新明  查庆庆  孙健  尹桂  徐正
作者单位:College of Chemistry and Materials Science Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu,Anhui 241000,China,College of Chemistry and Materials Science,Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu,Anhui 241000,China,College of Chemistry and Materials Science,Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu,Anhui 241000,China,College of Chemistry and Materials Science,Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu,Anhui 241000,China,College of Chemistry and Materials Science,Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu,Anhui 241000,China,State Key Laboratory of Coordination Chemistry,Coordination Chemistry Institute,Nanjing University,Nanjing,Jiangsu 210093,China,State Key Laboratory of Coordination Chemistry,Coordination Chemistry Institute,Nanjing University,Nanjing,Jiangsu 210093,China
摘    要:1,2-(1-Acridin-10'-y1-2-aza-2-methylprop-1,3-ylene)fullerene was synthesized firstly and characterized byUV-Vis,~1H NMR,~(13)C NMR and electrospray ionization mass spectroscopy,which is capable of forming a stablecomplex with zinc tetraphenylporphyrin via the axial ligafion.The steady state fluorescence studies show efficientquenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C_(60).

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