Integrated Discussion on Stereogenicity and Chirality for Restructuring Stereochemistry |
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Authors: | Shinsaku Fujita |
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Affiliation: | (1) Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyoku, Kyoto, 606-8585, Japan |
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Abstract: | To discuss the difference between stereogenicity and chirality, we propose the concept of RS-stereoisomeric groups. Beginning with this concept, we have further proposed the concepts of holantimers, stereoisograms, and RS-stereogenicity. Thereby, we have clarified that the concept of RS-stereogenicity, but not conventional stereogenicity, is closely related to chirality. Thus, five RS-stereogenicity types are defined and examined to discuss the difference between stereogenicity and chirality. Combinatorial enumerations have also been studied by considering the RS-stereogenicity. |
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Keywords: | stereochemistry stereogenicity chirality diastereomer |
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