Unimolecular decay of hydrogen-bonded cluster ions |
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Authors: | D Spangenberg C Janzen K Kleinermanns |
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Institution: | Institut für Physikalische Chemie und Elektrochemie I, Heinrich Heine-Universit?t, Universit?tsstrasse 1, 40225 Düsseldorf, Germany, DE
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Abstract: | The unimolecular decay of the hydrogen-bonded phenol(H2O)4
+ cluster ion was studied both experimentally and theoretically. The ion is formed by resonant two-color two-photon ionization
of the neutral cluster. If the second color exceeds the dissociation threshold of the ion, fragmentation occurs on a microsecond
time scale. By analyzing the time-of-flight (TOF) signal of the metastable ions at different excess energies the dependence
of the fragmentation rate on the excess energy can be deduced. These experimental rates are compared to microcanonical decay
constants k(E) calculated from Rice–Ramsperger–Kassel–Marcus (RRKM) theory based on ab initio data solely.
Received: 8 March 2000 / Revised version: 28 April 2000 / Published online: 5 October 2000 |
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Keywords: | PACS: 36 40 Qv |
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