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3D topography design of membranes for enhanced mass transport
Authors:P Izák  MH Godinho  P Brogueira  JL Figueirinhas  JG Crespo
Institution:1. REQUIMTE/CQFB, Dept. de Química, FCT-Universidade Nova de Lisboa, Campus da Caparica, P-2829-516 Caparica, Portugal;2. Dept. de Ciência dos Materiais and CENIMAT, FCT-Universidade Nova de Lisboa, Campus da Caparica, P-2829-516 Caparica, Portugal;3. Dept. de Física, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisboa Codex, Portugal;4. Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic
Abstract:This work describes the process of fabrication of 3D topography membranes and the fully quantitative characterisation of their topography using atomic force microscopy (AFM), small-angle light scattering (SALS), scanning electron microscopy (SEM) and polarizing optical microscopy (POM). The use of these membranes and the impact of the 3D membrane topography on the enhancement of mass transport during solute recovery (hexyl acetate) from a viscous room temperature ionic liquid 1-n-butyl-3-methyl-imidazolium tetrafluoroborate (C4mim] BF4]) by organophilic pervaporation is presented and discussed.
Keywords:Membrane topography  3D topography  Ionic liquids  Mass transport  Pervaporation
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