Ring-opening Polymerization of ε-Caprolactone by Lanthanide Tris(2,6-dimethylphenolate)s |
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作者姓名: | 张丽芳 沈之荃 于翠萍 |
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作者单位: | Institute of Polymer Science,Zhejiang University,Hangzhou,Zhejiang 310027,China,Department of Chemistry,Shanxi Normal University,Linfen,Shanxi 041004,China,Institute of Polymer Science,Zhejiang University,Hangzhou,Zhejiang 310027,China,Institute of Polymer Science,Zhejiang University,Hangzhou,Zhejiang 310027,China |
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基金项目: | theNationalNaturalScienceFoundationofChina (Nos .2 0 1740 33and 2 0 2 5 40 0 1) ,theMajorStateBasicResearchDevelopmentProgram (No .G19990 6 480 1)andtheCommitteeofScienceandTechnologyofZhejiangProvince |
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摘 要: | Ring openingpolymerizationofCLisamainrouteofpreparingbiodegradableandbiocompatiblePCL ,forwhichtherehasbeengrowinginterestinthedevelopmentofeffi cientinitiatorsforthering openingpolymerizationofCL .Recently ,rareearthcompoundsasinitiatorshavebeenat tractingincreasingattentionbecauseoftheirlowtoxicityandhighefficiency .Ourgroupreportedaseriesofrareearthcatalystsforthering openingpolymerizationandcopolymerizationofCL .1 5Thispaperdealswiththering openingpolymerizationofCLinitiatedwithLn(OD…
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关 键 词: | ring-opening polymerization ε-caprolactone lanthanide tris(2 6-dimethylphenolate) |
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