| Ring-opening Polymerization of ε-Caprolactone by Lanthanide Tris(2,6-dimethylphenolate)s |
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| 作者姓名： | 张丽芳 沈之荃 于翠萍 |
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| 作者单位： | Institute of Polymer Science，Zhejiang University，Hangzhou，Zhejiang 310027，China，Department of Chemistry，Shanxi Normal University，Linfen，Shanxi 041004，China，Institute of Polymer Science，Zhejiang University，Hangzhou，Zhejiang 310027，China，Institute of Polymer Science，Zhejiang University，Hangzhou，Zhejiang 310027，China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (Nos .2 0 1740 33and 2 0 2 5 40 0 1) ,theMajorStateBasicResearchDevelopmentProgram (No .G19990 6 480 1)andtheCommitteeofScienceandTechnologyofZhejiangProvince |
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| 摘 要： | Ring openingpolymerizationofCLisamainrouteofpreparingbiodegradableandbiocompatiblePCL ,forwhichtherehasbeengrowinginterestinthedevelopmentofeffi cientinitiatorsforthering openingpolymerizationofCL .Recently ,rareearthcompoundsasinitiatorshavebeenat tractingincreasingattentionbecauseoftheirlowtoxicityandhighefficiency .Ourgroupreportedaseriesofrareearthcatalystsforthering openingpolymerizationandcopolymerizationofCL .1 5Thispaperdealswiththering openingpolymerizationofCLinitiatedwithLn(OD…
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| 关 键 词： | ring-opening polymerization ε-caprolactone lanthanide tris(2 6-dimethylphenolate) |
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