| 光学活性和手性光谱的溯源和发展 |
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| 引用本文： | 章慧,齐爱华,李丹,李荣兴. 光学活性和手性光谱的溯源和发展[J]. 大学化学, 2022, 37(1): 220-235. DOI: 10.3866/PKU.DXHX202105009 |
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| 作者姓名： | 章慧 齐爱华 李丹 李荣兴 |
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| 作者单位： | 厦门大学化学化工学院,福建厦门361005,大连华洋分析仪器有限公司,辽宁大连116001 |
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| 摘 要： | 概述了19世纪以来光学活性和手性光谱的发现和发展,着重对旋光色散(ORD)、电子圆二色(ECD)和振动圆二色(VCD)光谱的发展背景和基本原理作出介绍。其中特别提及华人科学家徐光宪和徐云洁在手性光谱发展历程中的杰出贡献。
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| 关 键 词： | 光学活性和手性光谱史 旋光色散(ORD) 电子圆二色(ECD) 振动圆二色(VCD) |
Traceability and Development of Optical Activity and Chiroptical Spectroscopy |
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| Hui Zhang,Aihua Qi,Dan Li,Rongxing Li. Traceability and Development of Optical Activity and Chiroptical Spectroscopy[J]. University Chemistry, 2022, 37(1): 220-235. DOI: 10.3866/PKU.DXHX202105009 |
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| Authors: | Hui Zhang Aihua Qi Dan Li Rongxing Li |
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| Affiliation: | (College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian Province,China;Dalian Huayang Analytical Instruments Co.,Ltd.,Dalian 116001,Liaoning Province,China) |
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| Abstract: | This paper presents a comprehensive overview on the discovery and development of optical activity and chiroptical spectroscopy since the nineteenth century, with emphasis on the background and basic principles of the development of optical rotatory dispersion(ORD), electron circular dichroism(ECD) and vibrational circular dichroism(VCD) spectroscopy. Therein, the outstanding contributions of Chinese scientists Guangxian Xu and Yunjie Xu in the development of chiroptical spectroscopy are specifically mentioned. |
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| Keywords: | History of optical activity and chiroptical spectroscopy Optical rotatory dispersion(ORD) Electron circular dichroism(ECD) Vibrational circular dichroism(VCD) |
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