| Synthesis and Crystal Structure of a Two-dimensional Sil-ver(I)-Iron(III) Heteronuclear Coordination Polymer:{[Ag_4Fe_2(SCN)_(12)(H_2O)_2][(inaH)_2(H_2O)_2]}_n |
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| 作者姓名： | 李秀玲 童明良 牛德仲 陈久桐 |
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| 作者单位： | Department of Chemistry，Xuzhou Normal University，School of Chemistry & Chemical Engineering，Zhongshan University，Department of Chemistry，Xuzhou Normal University，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences Xuzhou，Jiangsu 221116，China，Guangzhou，Gongdong 510275，China，Xuzhou，Jiangsu 221116，China，Fuzhou，Fujian 350002，China |
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| 摘 要： | Introduction Molecules containing different kinds of metal ions play an important role in molecular magnetism.1-3 So considerable attention has been paid to synthesizing heteronuclear complexes.1-4 As a potential bridging ligand, thiocyanate can coordinate to a harder metal center and softer ones with N and S atoms respectively. The complexes of thiocyanate and representative hard acidFe(III) ions usually have a six-coordinate octahe-dral structure such as Fe(SCN)n]3-n and (Bu4N)4Ag2-F…
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Synthesis and Crystal Structure of a Two-dimensional Sil-ver(I)-Iron(III) Heteronuclear Coordination Polymer:{[Ag_4Fe_2(SCN)_(12)(H_2O)_2][(inaH)_2(H_2O)_2]}_n |
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| LI,Xiu-Ling,a TONG,Ming-Liangb NIU,De-Zhonga CHEN,Jiu-Tongc a.Synthesis and Crystal Structure of a Two-dimensional Sil-ver(I)-Iron(III) Heteronuclear Coordination Polymer:{[Ag_4Fe_2(SCN)_(12)(H_2O)_2][(inaH)_2(H_2O)_2]}_n[J].Chinese Journal of Chemistry,2004(1). |
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| Authors: | LI Xiu-Ling a TONG Ming-Liangb NIU De-Zhonga CHEN Jiu-Tongc a |
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| Institution: | LI,Xiu-Ling*,a TONG,Ming-Liangb NIU,De-Zhonga CHEN,Jiu-Tongc a Department of Chemistry,Xuzhou Normal University,Xuzhou,Jiangsu 221116,China b School of Chemistry & Chemical Engineering,Zhongshan University,Guangzhou,Gongdong 510275,China c Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| Abstract: | |
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| Keywords: | silver(I)-iron(III) heteronuclear polymer crystal structure thiocyanate bridge protonated isonico-tinic acid |
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