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Characterization of surface water on Au core Pt-group metal shell nanoparticles coated electrodes by surface-enhanced Raman spectroscopy
Authors:Jiang Yu-Xiong  Li Jian-Fen  Wu De-Yin  Yang Zhi-Lin  Ren Bin  Hu Jia-Wen  Chow Yuan L  Tian Zhong-Qun
Institution:State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China.
Abstract:We utilized the strategy of 'borrowing SERS activity', by chemically coating several atomic layers of a Pt-group metal on highly SERS-active Au nanoparticles, to obtain the first SERS (also Raman) spectra of surface water on Pt and Pd metals, and propose conceptual models for water adsorbed on Pt and Pd metal surfaces.
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