| 含甲巯咪唑杂环为端基的非环冠醚的合成 |
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| 引用本文： | 刘庆俭,石明理.含甲巯咪唑杂环为端基的非环冠醚的合成[J].有机化学,1992,12(5):509-513. |
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| 作者姓名： | 刘庆俭 石明理 |
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| 作者单位： | 山东师范大学化学系，山东师范大学化学系 山东，济南，250014，山东，济南，250014 |
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| 摘 要： | 本文以甲巯咪唑杂环为新的端基,在相转移催化条件合成了五个开链冠醚,这些化合物均通过元素分析、UV、IR 、^1H和^13CNMR波谱鉴定.
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| 关 键 词： | 紫外分光光度法 红外分光光度法 碳13核磁共振谱法 质子磁共振谱法 端基 冠醚 甲巯咪唑 |
Synthesis of noncyclic crown ethers with methimazol heterocycle as a terminal group |
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| LIU Qing-Jian,SHI Ming-Li.Synthesis of noncyclic crown ethers with methimazol heterocycle as a terminal group[J].Chinese Journal of Organic Chemistry,1992,12(5):509-513. |
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| Authors: | LIU Qing-Jian SHI Ming-Li |
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| Institution: | LIU Qing-Jian,SHI Ming-Li Department of Chemistry,Shandong Nornal University,250014 Jinan,Shandong |
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| Abstract: | Five noncyclic crown ethers I (n = 0, 1, 2, 3) and II with methimazol heterocycle as a terminal group were synthesized under phase-transfer catalytic conditions and characterized by elemental analyses, UV, IR, 1H and 13C NMR spectra. The preliminary studies reveal that II can coordinate rapidly with Hg2+, Au3+ and I with UO22+. |
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| Keywords: | noncyclic crown ether methimazol terminal group synthesis |
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