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8位取代吡咯甲川-BF2化合物的光物理行为
引用本文:元以中,姚祖光,孙真荣,曾和平,丁晶新. 8位取代吡咯甲川-BF2化合物的光物理行为[J]. 物理化学学报, 2001, 17(6): 555-559. DOI: 10.3866/PKU.WHXB20010617
作者姓名:元以中  姚祖光  孙真荣  曾和平  丁晶新
作者单位:Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237;Key Laboratory for Optical & Magnetic Resonance Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062
基金项目:国家自然科学基金(29676013)及光谱学与波谱学教育部重点实验室资助项目
摘    要:

关 键 词:吡咯甲川-BF2化合物  荧光光谱  荧光量子产率  三重态吸收光谱  
收稿时间:2000-11-17
修稿时间:2000-11-17

Photophysical Propertiesof 8-Substituted Pyrromethene-BF2 Complexes
Yuan Yi-Zhong. Photophysical Propertiesof 8-Substituted Pyrromethene-BF2 Complexes[J]. Acta Physico-Chimica Sinica, 2001, 17(6): 555-559. DOI: 10.3866/PKU.WHXB20010617
Authors:Yuan Yi-Zhong
Affiliation:Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237;Key Laboratory for Optical & Magnetic Resonance Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062
Abstract:Six novel pyrromethene BF2 complexes,of which five compounds have not been reported,were synthesized and characterized.Their relationships between st ructure and photophysical behavior were studied with the aid of fluorescence and triplet state absorption spectra.The results indicate that,compared to 8 alkyl pyrromethene BF2 complexes,the compounds containing 8 aryl exhibit high fluore scence quantum yield and rather low triplet state absorption.
Keywords:2 complexes',')  "  >Pyrromethene BF2 complexes  Fluorescence spectra  Fluorescence quantum yield  Triplet state absorption spectra
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