CO2 laser induced isomerization and photodissociation of 1,2-dichloroethylene |
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| Authors: | Keeichi Nagai Mikio Katayama |
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| Institution: | Department of Pure and Applied Sciences, College of General Education, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153, Japan |
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| Abstract: | Infrared photoisomerization of both trans- and cis-1,2-dichloroethylene molecules sensitized by SF6 has been observed by using a CO2 laser. The direct infrared photoisomerization has also been observed for the trans molecule. The reaction rate of the sensitized photoisomerization increases by 6 times as compared with the direct process. The dielectric breakdown induced by an intense laser pulse enhances a dissociative reaction. |
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