Determination of the spin sublevel origin of radiative and non-radiative decay routes of phosphorescing benzene derived from precision lifetime measurements |
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Authors: | N.G. Kilmer A.H. Kalantar |
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Affiliation: | Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2 |
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Abstract: | The increase in the phosphorescence lifetime as temperature is lowered has been quantitatively determined in the 2–30 K range. Applying the Boltzmann population expression yields the information that virtually none of the radiative decay originates from the lowest spin sublevel (A2g). |
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