Optical rotatory dispersion of rare earth crystal |
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| Authors: | Asok Ch. Sen Subhas Ch. Bera Mihir Chowdhury |
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| Affiliation: | Department of Physical Chemistry, Indian Association for the Cultivation of Science, and Jadavpur University, Calcutta-700032, India |
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| Abstract: | The ORD spectrum of optically active single crystal of praseodymium oxydiacetate has been studied in the visible range at 77 K. The results have been compared with those obtained in the cases of transition metal complexes and other RE complexes with optically active ligands, and correlated with the site symmetry of the RE ion in the crystal. The optical activity has been related to the magnetic dipole strengths of the transitions. |
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