Time resolved HF vibrational fluorescence from the IR photodissociation of SF6/H2 mixtures |
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Authors: | CR Quick Curt Wittig |
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Institution: | Electrical Engineering Department, University of Southern California, University Park, Los Angeles, California 90007 USA |
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Abstract: | Time resolved measurements of HF spontaneous emission, following the irradiation of SF6/H2 mixtures with the focused output from a CO2 TEA laser, are reported. Our results indicate that F atoms are produced directly by the photodissociation process, and that these atoms have a recoil energy which is ≤500 cm?1, and varies only slightly with the radiation intensity. Further, our results show a linear dependence of fluorescence intensity with laser energy, indicating that processes other than direct photodissociation may play a significant role in the ultimate fate of species excited by IR collisionless multiple photon absorption. |
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