On a new approximation in the theory of electrolyte solutions |
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| Authors: | W. Olivares D.A. McQuarrie |
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| Affiliation: | Department of Theoretical Chemistry, University of Oxford, Oxford, UK;Dyson Perrins Laboratory, University of Oxford, Oxford, UK |
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| Abstract: | We compare the results of a new approximation for the interionic radial distribution function developed previously by Olivares and McQuarrie to those from the nonlinear Poisson—Boltzmann equation for the highly-charged system of the spherical protein bearing a charge as 20 in an aqueous electrolyte solution. In particular, we use both approximations to predict the experimental results for protein titration, which are the experimental data to which the results of the Poisson—Boltzmann equation had been directed. |
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| Keywords: | To whom correspondence should be addressed at The King's School Canterbury Kent UK. |
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