The solvophobic effect in simple fluid mixtures |
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| Authors: | David Ronis Esteban Martina J.M. Deutch |
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| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA |
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| Abstract: | The “solvophobic” effect is the tendency of solute particles to cluster as the attractive interaction between solvent particles is strengthened. The potentials of mean force in the hypernetted chain approximation have been obtained for a simple fluid mixture consisting of two hard spheres immersed in a hard core/Yukawa tail solvent. The results clearly exhibit features attributable to the “solvophobic” effect. |
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