Kinetics of the reaction of solvated electrons with fluorobenzene in liquid ammonia |
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Authors: | E. San Roman P. Krebs U. Schindewolf |
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Affiliation: | Institut für Physikalische Chemie und Elektrochemie, Universität Karlsruhe, Karlsruhe, Germany |
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Abstract: | The rate of disappearance of solvated electrons by reaction with fluorobenzene in ammonia is accelerated by small concentrations of methanol; it also has a “negative activation energy” depending on the methanol concentration. The kinetic data suggest an exothermic electron attachment-detachment equilibrium with the fluorobenzene followed by a slower reaction of the electron adduct with the proton donating methanol. |
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