Combined experimental and master equation investigation of the multiwell reaction H + SO2 |
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| Authors: | Blitz Mark A Hughes Kevin J Pilling Michael J Robertson Struan H |
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| Institution: | School of Chemistry, University of Leeds, Leeds, LS2 9JT, U.K. |
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| Abstract: | The temperature and pressure dependence of the rate coefficient for the reaction H + SO2 has been measured using a laser flash photolysis/laser-induced fluorescence technique, for 295 10(3) atm, the latter proceeds directly from H + SO2, via the energized states of HOSO. The derived rate coefficients rely heavily on measurements of the reverse reaction, OH + SO, which has only been determined at temperatures up to 700 K. |
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