Total synthesis of sphingofungin F |
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| Authors: | Lee Kee-Young Oh Chang-Young Ham Won-Hun |
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| Institution: | College of Pharmacy, SungKyunKwan University, Suwon 440-746, Korea. |
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| Abstract: | reaction: see text] A concise, stereocontrolled synthesis of sphingofungin F was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr(2)-promoted gamma-alkoxy allylic stannane addition, and palladium(0)-catalyzed coupling of a vinyl iodide with an organozinc reagent. |
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