Highly enantioselective hydrogenation of enol acetates catalyzed by Ru-TunaPhos complexes |
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| Authors: | Wu Shulin Wang Weimin Tang Wenjun Lin Min Zhang Xumu |
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| Institution: | Department of Chemistry, The Pennsylvania State University, 152 Davey Laboratory, University Park 16802, USA. |
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| Abstract: | reaction: see text] The chiral disphosphines with tunable dihedral angles (TunaPhos) have been used for asymmetric hydrogenation of enol acetates and dihedral-angle-dependent enantioselectivities were observed. C2-TunaPhos has been proved to be effective for Ru-catalyzed asymmetric hydrogenation of electron-deficient and other enol acetates. |
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