A concise approach to (+)-1-epi-castanospermine |
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| Authors: | Tian-Jun Wu |
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| Institution: | Department of Chemistry and The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, PR China |
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| Abstract: | A concise enantioselective synthesis of (+)-1-epi-castanospermine (2) is described, which featured the use of chiral non-racemic tetramic acid derivative 5 as a synthetic equivalent of the challenging synthon A through a highly diastereoselective vinylogous Mukaiyama type reaction. |
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| Keywords: | Castanospermine Tetramic acid Synthon Mukaiyama type reaction |
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