Theoretical studies on the N-containing radicals formed in thermal decompositions of dimethyl- and diethyldiazenes |
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| Authors: | T K?rtvélyesi and L Seres |
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| Institution: | (1) Institute of General and Physical Chemistry, A. József University, Szeged, Hungary |
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| Abstract: | The geometries and energies of  1 and 2 radicals, formed in the thermal reaction of dimethyl- and diethyldiazenes, were investigated by means of UHF-MINDO/3. The stability of radicals was found greater than that of allyl radical. The calculated SOMO energies show a lower reactivity in H-abstraction reactions than that of alkyl and allyl radicals.
      UHF-MINDO/3               1 2,       - .   1   , .  SOMO  ,  .
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